bims-metalz Biomed News
on Metabolic causes of Alzheimer’s disease
Issue of 2024–07–21
three papers selected by
Mikaila Chetty, Goa University



  1. RSC Adv. 2024 Jul 12. 14(31): 22374-22392
      Silver metal, being a 3d transition metal in group 11 in the periodic table, is widely used in material science for its distinguished plasmonic properties. Nanoparticles (NPs) and nanoclusters (NCs) are widely used in sensing applications having a surface plasmon band and emissive properties, respectively. Mercury is one of the detrimental toxins and threats to various ecosystems. The distinction between nanoparticles and nanoclusters, the utility and toxicity of heavy metal mercury, fluorometric and colorimetric approaches to the recognition of mercury ions with NPs and NCs, the mechanism of detection, spot detection, and natural water sample analyses were illustrated in detail in this review article. Moreover, the sensing platform and analyte (Hg2+) fate were described for substantiating the mechanism. It was observed that NCs are mostly utilized for fluorometric approaches, while NPs are mostly employed for colorimetric approaches. Fluorometric detection is mainly quenching-based. However, sensing with enhancement was found in a few reports. Adulteration of other metals with silver particles often modifies the sensing platform.
    DOI:  https://doi.org/10.1039/d4ra04182h
  2. Chemosphere. 2024 Jul 17. pii: S0045-6535(24)01791-0. [Epub ahead of print] 142897
      Male infertility is a serious ongoing problem, whose causes have not yet been clearly identified. However, since human exposure to silver nanoparticles (AgNPs) has recently increased due to their beneficial properties, the present study aimed to determine the impact of small-size AgNPs on mouse spermatogonia (GC-1 spg) and spermatocytes [GC-2 spd(ts)] in in vitro models as well as the ability of these nanostructures to induce inflammation. The results showed a significant dose- and time-dependent decrease in the metabolic activity in both cell models, which was correlated with an increase in the intracellular ROS level. Moreover, increased activity of caspase-9 and -3, together with enhanced expression of CASP3 and p(S15)-p53 proteins, was detected. Further studies indicated a decrease in ΔΨm after the AgNP-treatment, which proves induction of apoptosis with engagement of an intrinsic pathway. The PARP1 protein expression, the activity and protein expression of antioxidant enzymes, the GSH level, and the increased level of p-ERK1/2 indicate not only the engagement of DNA damage but also the occurrence of oxidative stress. The small-size AgNPs were able to induce inflammation, proved by increased protein expression of NF-κB, p-IκBα, and NLRP3, which indicate damage to spermatogonia and spermatocyte cells. Moreover, the PGC-1α/PPARγ and NRF2/Keap1 pathways were engaged in the observed effect. The spermatogonial cells were characterized by a stronger inflammation-based response to AgNPs, which may be correlated with the TNFα/TRAF2-based pathway. Summarizing, the obtained results prove that AgNPs impair the function of testis-derived cells by inducing the redox imbalance and inflammation process; therefore, these NPs should be carefully implemented in the human environment.
    Keywords:  apoptosis; male fertility; reprotoxicity; silver nanoparticles; spermatocytes; spermatogonia
    DOI:  https://doi.org/10.1016/j.chemosphere.2024.142897
  3. IBRO Neurosci Rep. 2024 Jun;16 373-394
      Superoxide dismutase (SOD) is a common antioxidant enzyme found majorly in living cells. The main physiological role of SOD is detoxification and maintain the redox balance, acts as a first line of defence against Reactive nitrogen species (RNS), Reactive oxygen species (ROS), and other such potentially hazardous molecules. SOD catalyses the conversion of superoxide anion free radicals (O 2 -.) into molecular oxygen (O 2) and hydrogen peroxide (H 2O 2) in the cells. Superoxide dismutases (SODs) are expressed in neurons and glial cells throughout the CNS both intracellularly and extracellularly. Endogenous oxidative stress (OS) linked with enlarged production of reactive oxygen metabolites (ROMs), inflammation, deregulation of redox balance, mitochondrial dysfunction and bioenergetic crisis are found to be prerequisite for neuronal loss in neurological diseases. Clinical and genetic studies indicate a direct correlation between mutations in SOD gene and neurodegenerative diseases, like Amyotrophic Lateral Sclerosis (ALS), Huntington's disease (HD), Parkinson's Disease (PD) and Alzheimer's Disease (AD). Therefore, inhibitors of OS are considered as an optimistic approach to prevent neuronal loss. SOD mimetics like Metalloporphyrin Mn (II)-cyclic polyamines, Nitroxides and Mn (III)- Salen complexes are designed and used as therapeutic extensively in the treatment of neurological disorders. SODs and SOD mimetics are promising future therapeutics in the field of various diseases with OS-mediated pathology.
    Keywords:  And oxidative stress; Neurodegenerative diseases; Neurological disorders; Reactive oxygen species; Superoxide anions; Superoxide dismutase
    DOI:  https://doi.org/10.1016/j.ibneur.2023.11.007